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06_chapter1.pdf

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1.1

CHAPTER 1

OVERVIEW OF NANOMATERIALS, PEROVSKITE OXIDES AND PHOTOCATALYTIC APPLICATIONS

INTRODUCTION TO NANOMATERIALS

Nanoscience and nanotechnology primarily deal with the synthesis, characterization, exploration, and exploitation of nanostructured materials. Nanotechnology is the term used to cover the design, construction and utilization of functional structures with at least one characteristic dimension measured in nanometres. Such materials and systems can be designed to exhibit novel and significantly improved physical, chemical and biological properties, phenomena and processes as a result of the limited size of their constituent particles or molecules. The reason for such interesting and useful behaviour is that when characteristic structural features are intermediate in extent between isolated atoms and bulk macroscopic materials; i.e., in the range of about 10-9 m to 10-7 m (1 to 100 nm), the objects may display physical attributes substantially different from those displayed by either atoms or bulk materials. Nanostructures constitute a bridge between molecules and infinite bulk systems. Individual nanostructures include clusters, quantum dots, nanocrystals, nanowires, and nanotubes, while collections of nanostructures involve arrays, assemblies and superlattices of the individual nanostructures. The uniqueness of the structural characteristics, energetics, response, dynamics, and chemistry of nanostructures constitutes the basis of nanoscience. Suitable control of the properties and response of nanostructures can lead to new devices and technologies (Gogotsi 2006).

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 Supercritical Fluid Extraction 06_chapter1.pdf Page 001
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